|
|
1-deoxy-D-threo-hexo-2,5-diulose_6-phosphate + L-aspartate_4-semialdehyde <=> 2-amino-3,7-dideoxy-D-threo-hept-6-ulosonate + 2,3-dioxopropyl_phosphate
|
2.2.1.10
2-amino-3,7-dideoxy-D-threo-hept-6-ulosonate synthase
|
–
|
| |
BRENDA:
BR50116
KEGG:
R08568
MetaCyc:
RXN-10031
|
|
|
|
shikimate + ATP <=> H+ + 3-phosphoshikimate + ADP
|
2.7.1.71
shikimate kinase
|
–
|
| |
BRENDA:
BR47798
KEGG:
R02412
MetaCyc:
SHIKIMATE-KINASE-RXN
SABIO-RK:
2350
|
|
|
|
methylglyoxal + D-fructose_1,6-bisphosphate <=> D-glyceraldehyde_3-phosphate + 1-deoxy-D-threo-hexo-2,5-diulose_6-phosphate
|
2.2.1.11
6-deoxy-5-ketofructose 1-phosphate synthase
|
–
|
| |
BRENDA:
BR50117
KEGG:
R10049
MetaCyc:
RXN-10053
|
|
|
|
L-lactaldehyde + NADP+ <=> methylglyoxal + NADPH + H+
|
1.1.1.156
glycerol 2-dehydrogenase (NADP+)
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.21
aldose reductase
1.1.1.283
methylglyoxal reductase (NADPH)
1.1.1.71
alcohol dehydrogenase [NAD(P)+]
1.1.1.72
glycerol dehydrogenase (NADP+)
1.1.1.78
methylglyoxal reductase (NADH)
1.2.1.49
2-oxoaldehyde dehydrogenase (NADP+)
|
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR48480;
BS139557
KEGG:
R02260
MetaCyc:
1.1.1.283-RXN
SABIO-RK:
550;
9214
|
|
|
|
3-phosphoshikimate + phosphoenolpyruvate <=> 5-enolpyruvylshikimate_3-phosphate + phosphate
|
2.5.1.19
3-phosphoshikimate 1-carboxyvinyltransferase
|
–
|
| |
BRENDA:
BR47516
KEGG:
R03460
MetaCyc:
2.5.1.19-RXN
SABIO-RK:
3254
|
|
|
|
shikimate + NADP+ <=> 3-dehydroshikimate + NADPH + H+
|
1.1.1.24
quinate dehydrogenase
1.1.1.25
shikimate dehydrogenase
1.1.1.282
quinate/shikimate dehydrogenase
|
–
–
–
|
| |
BRENDA:
BR29283;
BS428938
KEGG:
R02413
MetaCyc:
RXN-11174;
SHIKIMATE-5-DEHYDROGENASE-RXN
SABIO-RK:
2351
|
|
|
|
phosphoenolpyruvate + D-erythrose_4-phosphate + H2O <=> 3-deoxy-D-arabino-hept-2-ulosonate_7-phosphate + phosphate
|
2.5.1.54
3-deoxy-7-phosphoheptulonate synthase
2.5.1.55
3-deoxy-8-phosphooctulonate synthase
|
–
–
|
| |
BRENDA:
BR47668;
BS410936
KEGG:
R01826
MetaCyc:
DAHPSYN-RXN
SABIO-RK:
1910
|
|
|
|
3-deoxy-D-arabino-hept-2-ulosonate_7-phosphate <=> 3-dehydroquinate + phosphate
|
4.2.1.10
3-dehydroquinate dehydratase
4.2.3.4
3-dehydroquinate synthase
|
–
–
|
| |
BRENDA:
BR16093
KEGG:
R03083
MetaCyc:
3-DEHYDROQUINATE-SYNTHASE-RXN
SABIO-RK:
2923
|
|
|
|
enolaldehyde <=> methylglyoxal
|
0.0.0.0
|
–
|
| |
BRENDA:
BR52893
MetaCyc:
RXN-10054
|
|
|
|
2-amino-3,7-dideoxy-D-threo-hept-6-ulosonate + H2O + NAD+ <=> 3-dehydroquinate + NH3 + NADH + H+
|
1.4.1.24
3-dehydroquinate synthase II
|
–
|
| |
BRENDA:
BR50242
KEGG:
R08569
MetaCyc:
RXN-10032
|
|
|
|
5-enolpyruvylshikimate_3-phosphate <=> phosphate + chorismate
|
4.2.3.5
chorismate synthase
|
–
|
| |
BRENDA:
BR16094
KEGG:
R01714
MetaCyc:
CHORISMATE-SYNTHASE-RXN
SABIO-RK:
1826
|
|
|
|
3-dehydroquinate <=> H2O + 3-dehydroshikimate
|
4.2.1.10
3-dehydroquinate dehydratase
|
–
|
| |
BRENDA:
BR401
KEGG:
R03084
MetaCyc:
3-DEHYDROQUINATE-DEHYDRATASE-RXN
SABIO-RK:
2924
|
|
|
|
dihydroxyacetone_phosphate <=> methylglyoxal + phosphate
|
4.1.2.17
L-fuculose-phosphate aldolase
4.2.3.3
methylglyoxal synthase
5.3.1.1
triose-phosphate isomerase
|
–
–
–
|
| |
BRENDA:
BR16092
KEGG:
R01016
MetaCyc:
METHGLYSYN-RXN
SABIO-RK:
176
|
|
